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This work quantifies the impact of gas-dust drift on molecular hydrogen formation efficiency on interstellar dust grains using an event-driven kinetic Monte Carlo model. The study reveals that while increased collision rates due to drift can enhance formation under constant sticking assumptions, energy-dependent sticking probabilities lead to significant suppression, particularly on carbonaceous grains. The findings highlight that gas-dust drift's influence on H$_2$ formation is complex, mediated by competing effects on collision rates and sticking, with Eley-Rideal reactions becoming dominant under strong drift.
Gas-dust drift can suppress H$_2$ formation by up to 99% in dynamically active interstellar environments, contradicting simple collision rate assumptions.
Molecular hydrogen is predominantly formed on dust-grain surfaces in the interstellar medium, where relative gas-dust motion can arise in dynamically active environments. While the dependence of H$_2$ formation on grain temperature and surface properties is well studied, the impact of gas-dust drift has received little attention. We investigate how gas-dust drift modifies H$_2$ formation, focusing on the competition between the drift-enhanced H-atom collision rate and reduced sticking at higher impact energies. We use an event-driven kinetic Monte Carlo model that follows individual H atoms on spherical silicate and carbonaceous grains, including adsorption, surface migration, thermal desorption, and Langmuir-Hinshelwood (LH) and Eley-Rideal (ER) reactions. Drift is described by a shifted Maxwellian velocity distribution, and we compare constant and impact-energy-dependent sticking probabilities. Drift produces increasingly anisotropic distributions of adsorbed H and H$_2$ formation across the grain surface. Assuming constant sticking, increasing drift enhances H$_2$ formation through the higher collision rate, with efficiencies up to $\epsilon=0.3-0.4$. With energy-dependent sticking, strong drift instead suppresses formation on both materials, reducing efficiencies to $\epsilon=0.01-0.03$. Carbonaceous grains remain efficient to higher dust temperatures than silicate grains. ER reactions dominate over most of the investigated parameter space and become increasingly important at strong drift as the reduced surface population suppresses LH reactions. Thus, enhanced collision rates under gas-dust drift do not necessarily increase H$_2$ formation. Models of dynamically active environments should account for both relative gas-dust velocities and their effects on sticking.