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Linac Coherent Light Source, SLAC National Accelerator Laboratory, 2575 Sand Hill Road, Menlo Park, CA 94025, USA., Department of Chemistry, University of California, Davis, California 95616, USA.
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Ultrafast X-ray spectroscopy reveals the hidden choreography of electronic state transitions that drive Norrish Type-I reactions, pinpointing the long-lived $^3n\pi^*$ state as the key player.